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SOLVED:Which of the following compound can show geometrical isomerism in its tautomeric form?
2021年10月5日
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Compound (X) (C, H, O) gives a red precipitate with cupric ions in basic medium. This compound on keeping in excess of acetic acid with some catalyst forms a polyacetal (Y). (Y) does not respond to Cu^2 /OH . (X) on HIO4 oxidation forms formic acid (4 moles) and formaldehyde (1 mole only). With PhNHNH2/HCl , forms red coloured product (Z). By consuming 2 moles of the PhNHNH2/HCl , (Z) is also obtained by the given compound (W).The compound (Y) does not give a positive test with Cu^2 /OH^- ,
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SOLVED: 5-Bromouracil is an analog of thymine that normally pairs with adenine. Its rare tautomeric form pairs with adenine. Show the steps (i.e., several replications) by which 5-bromouracil causes the GC base pair shown below to change to an AT base pair. Show the point at which the rare tautomeric form of 5-bromouracil occurs. Show both products of all divisions in which 5-bromouracil is involved. Do not show chemical structures.
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SOLVED:Write the structures of other tautomeric forms of adenine,… | Numerade
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Keto-enol tautomerism is a special type of isomerism involving the 1,3 shift of a proton. There exists an equilibrium between keto and enol forms. In most cases keto form is more stable while in certain cases enol form is favoured. One which is not a tautomeric pair among the following is : | Numerade
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